Glass major element geochemical data on Late Quaternary tephra deposits from the Main Ethiopian Rift volcanoes. These data were acquired using Electron Microprobe Analysis, and secondary standard data (MPI-DING glasses) are also included. All samples were given a unique name related to the outcrop from which they were obtained. Outcrops are named "MER" followed by a 3-digit number (e.g. MER153). Samples from a given outcrops are given the same name, followed by a letter (e.g. MER153A). Outcrop localities, with GPS coordinates (Lat Long WGS84) and brief description of the geology are also included. These data are published as Supplementary Files to a paper published in Journal of Volcanology and Geothermal Research: Fontijn et al (2018), https://doi.org/10.1016/j.jvolgeores.2018.02.001.