The G-BASE programme involves systematic sampling and the determination of chemical elements in samples of stream sediment, stream water and soil, to build up a picture of the surface chemistry of the UK. G-BASE for SW England is the most recent area of the UK sampled by this on-going project The average sample density for stream sediments is approximately one site per 2km square. Density for soils in SW England is variable across the area, ranging from 1 per 2km square to one per 5km square, depending on underlying parent material. Analytical precision is high with strict quality control to ensure countrywide consistency. Results have been standardised to ensure continuity with existing G-BASE geochemical data. The data provide baseline information on the natural abundances of elements, against which anomalous values due to such factors as mineralisation and industrial contamination may be compared. Analytical data for the sub150 microns fraction of stream sediment and the sub 2mm fraction of soil samples are available for some or all of: Ag, Al, As, Ba, Bi, Br, Ca, Cd, Ce, Cl, Co, Cr, Cs, Cu, Fe, Ga, Ge, Hf, I, In, K, La, Mg, Mn, Mo, Na, Nb, Nd, Ni, P, Pb, Rb, S, Sb, Sc, Se, Si, Sm, Sn, Sr, Ta, Te, Th, Ti, Tl, U, V, W, Y, Yb, Zn, and Zr.