The Estimated Ambient Background Soil Chemistry England and Wales dataset indicates the estimated geometric mean topsoil Arsenic(As), Cadmium (Cd), Cr (Chromium), Nickel (Ni) and Lead (Pb) concentrations (mg kg-1). The soil chemistry data is based on GBASE (Geochemical Baseline Survey of the Environment) soil geochemical data where these are available. Elsewhere the stream sediment data are converted to surface soil equivalent potentially harmful element (PHE) concentrations. This dataset covers England and Wales but data is available for the whole of Great Britain, with the exception of the London area where an inadequate number of geochemical samples are available at the moment.